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108 Personal Protective Equipment: Basic
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Glove Selection Chart

You can use this OSHA chart to help select the proper gloves for the job. The chart shows different types of glove materials and the chemicals they are good for protecting against.

Type Advantages Disadvantages Use Against
Natural rubber Low cost, good physical properties, dexterity Poor vs. oils, greases, organics. Frequently imported; may be poor quality Bases, alcohols, dilute water solutions; fair vs. aldehydes, ketones
Natural rubber blends Low cost, dexterity, better chemical resistance than natural rubber vs. some chemicals Physical properties frequently inferior to natural rubber Same as natural rubber
Polyvinyl chloride (PVC) Low cost, very good physical properties, medium cost, medium chemical resistance Plasticizers can be stripped; frequently imported; may be poor quality Strong acids and bases, salts, other water solutions, alcohols
Neoprene Medium cost, medium chemical resistance, medium physical properties N/A Oxidizing acids, anilines, phenol, glycol ethers
Nitrile Low cost, excellent physical properties, dexterity Poor vs. benzene, methylene chloride, trichloroethylene, many ketones Oils, greases, aliphatic chemicals, xylene, perchloroethylene, trichloroethane; fair vs. toluene
Butyl Specialty glove, polar organics Expensive, poor vs. hydrocarbons, chlorinated solvents Glycol ethers, ketones, esters
Polyvinyl alcohol (PVA) Specialty glove, resists a very broad range of organics, good physical properties Very expensive, water sensitive, poor vs. light alcohols Aliphatics, aromatics, chlorinated solvents, ketones (except acetone), esters, ethers
Fluoro- elastomer (Viton) Specialty glove, organic solvents Extremely expensive, poor physical properties, poor vs. some ketones, esters, amines Aromatics, chlorinated solvents, also aliphatics and alcohols
Norfoil (Silver Shield) Excellent chemical resistance Poor fit, easily punctures, poor grip, stiff Use for Hazmat work

For more information see OSHA's Field Safety and Health System (SHMS) Manual, Chapter 8, Appendix C: Chemical Resistant Glove Selection.